MAGNEŢI MOLECULARI – TRECEREA DE LA LIGANZI DE TIP SALEN SPRE TIOSEMICARBAZONE

oleh: Mihail SECU

Format: Article
Diterbitkan: Moldova State University 2016-02-01

Deskripsi

<p class="ListparagrafCxSpFirst">Au fost scoşi în evidenţă compuşi coordinativi ai manganului(III) cu liganzi tip <em>Salen</em> ce posedă proprietăţi de magneţi moleculari (SMM) sau lanţuri magnetice (SCM). A fost relatat principiul de asamblare a bis(saliciliden)izotiosemi­car­ba­zi­da­ţilor similari liganzilor de tip <em>Salen</em>, pentru identificarea şi descrierea unor noi metode raţionale de sinteză a mole­culelor magnetice şi a lanţurilor magnetice, având în calitate de building block aceşti complecşi de mangan(III).</p><p class="ListparagrafCxSpLast"> </p><h3>SINGLE MOLECULE MAGNETS– Switching from SALEN type ligands to thiosemicarbazones</h3><p class="ListparagrafCxSpFirst">There were highlighted manganese(III) coordination compounds with <em>Salen</em> type ligands, which exhibit single molecule magnet (SMM) and single chain magnet (SCM) behaviour. It was narrated the principle of assembly bis(salicylidene)isothio­semicarbazide similar with<em> Salen</em> type ligands, for identify and describe the new methods of rational synthesis of single molecule magnets and single chain magnets, which have as building blocks these manganese(III) complexes.<strong></strong></p><p class="ListparagrafCxSpLast"> </p>