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The first soil map of the whole Aosta Valley Region was produced at the 1:100,000 scale. We used 691 soil profiles, attributed to 16 Cartographic (soil) Units, spatialized using a Maximum Likelihood Estimation model available in ArcGIS software. Six maps were used as base layers, representing the most important soil-forming factors: parent material, vegetation/land use, mean annual precipitation, elevation, absolute aspect and slope angle. The Maximum Likelihood Estimation was followed by an expert-based check that led to a re-assignment of some wrongly attributed cartographic polygons. The validation process revealed that the User’s and Producer’s Accuracies were rather high (between 47.5% and 84.4% for common soil types). A particularly high pedodiversity, associated to strong geological, vegetational and climatic gradients was observed.