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Cs(Pb,Mn)Br<sub>3</sub> Quantum Dots Glasses with Superior Thermal Stability for Contactless Electroluminescence Green−Emitting LEDs
oleh: Aochen Du, Wenxiao Zhao, Yu Peng, Xinzhi Qin, Zexi Lin, Yun Ye, Enguo Chen, Sheng Xu, Tailiang Guo
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2022-12-01 |
Deskripsi
CsPbX<sub>3</sub> (X = Cl, Br or I) perovskite quantum dots (PQDs) have gained increasing interest due to their superior performance in photoelectric applications. In our work, a series of Mn<sup>2+</sup> doped CsPbBr<sub>3</sub> PQDs were successfully prepared in glasses by melt quenching and in situ crystallization technique. Due to the <sup>4</sup>T<sub>1</sub> (<sup>4</sup>G)→<sup>6</sup>A<sub>1</sub> (<sup>6</sup>S) transition of Mn<sup>2+</sup>, a slight red shift from 510 nm to 516 nm was found, with the FWHM expansion from 18 nm to 26 nm. The PQDs@glasses showed excellent thermal stability, and the exciton binding energy reached a high level of 412 meV. The changes of the electronic structure after Mn doping CsPbBr<sub>3</sub> can be demonstrated by first principles. Finally, a contactless electroluminescence device with the PQDs@glasses was designed based on the principle of electromagnetic induction, which is a potential application for detecting distance in sterile and dust−free environments.