Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Sensitivity of stratospheric Br<sub>y</sub> to uncertainties in very short lived substance emissions and atmospheric transport
oleh: I. Wohltmann, S. Fueglistaler, R. Schofield, M. Rex
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2011-02-01 |
Deskripsi
We evaluate the sensitivity of Br<sub>y</sub> entering the stratosphere with a simplified model that allows calculations over a wide parameter range for parameters that are currently poorly quantified. The model examines the transport process uncertainties in the source concentrations and lifetimes, in the convective parameterization and in the inorganic bromine washout process due to dehydration. Source concentrations at the surface and lifetimes were found to have a slight effect on the resultant Br<sub>y</sub> (1 ppt), however this was highly dependent upon, with increasing significance, the BL component of convectively delivered air. Efficiency of convective delivery of boundary layer (BL) air to the tropical tropopause layer (TTL) along with washout at the CPT were found to substantially affect Br<sub>y</sub> at 400 K – altering the delivered Br<sub>y</sub> by 3.3 ppt and 2.9 ppt, respectively. We find that the results critically depend on free tropospheric bromine source gas concentrations due to dilution of convective updrafts, and the processes that control free tropospheric bromine source gas concentrations require further attention.