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Inhibition of oxygen dimerization by local symmetry tuning in Li-rich layered oxides for improved stability
oleh: Fanghua Ning, Biao Li, Jin Song, Yuxuan Zuo, Huaifang Shang, Zimeng Zhao, Zhen Yu, Wangsheng Chu, Kun Zhang, Guang Feng, Xiayan Wang, Dingguo Xia
Format: | Article |
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Diterbitkan: | Nature Portfolio 2020-10-01 |
Deskripsi
Li-rich layered oxide cathodes show high capacities in Li-ion batteries but suffer from structural degradation via O–O dimerization. Here, the authors present local-symmetry-tuned Li2RuO3 with oxygen redox involving a telescopic O–Ru–O configuration avoiding O2 release, enhancing cycling stability.