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Electron-Beam Sintering of Al<sub>2</sub>O<sub>3</sub>-Cr-Based Composites Using a Forevacuum Electron Source
oleh: Aleksandr Klimov, Ilya Bakeev, Anna Dolgova, Efim Oks, Van Tu Tran, Aleksey Zenin
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2022-10-01 |
Deskripsi
We describe our studies of the influence of Cr content in an Al<sub>2</sub>O<sub>3</sub>-Cr composite on its thermal and electrical conductivity properties during and after electron-beam sintering in the forevacuum range of pressure. Sintering was carried out using a plasma-cathode forevacuum-pressure electron source of an original design, capable of processing non-conducting materials directly. It is shown that the chromium content affects the efficiency of the beam power transfer to the irradiated composite. The efficiency decreases with increasing chromium content. Measurement of the composite’s coefficient of thermal conductivity, in the temperature range 50–400 °C, shows that it varies almost linearly from 25 W/(m∙K) to 68 W/(m∙K) as the Cr content in the composite increases from 25% to 75% wt. The electrical conductivity properties after sintering exhibit a non-linear behavior. The conduction activation energy E<sub>a</sub>, measured via the dependence of the current through composites of different compositions, is slightly lower than the Al<sub>2</sub>O<sub>3</sub> band-gap. The addition of metallic Cr results in a disproportionate decrease in E<sub>a</sub>, almost by an order of magnitude, from 6.9 eV to 0.68 eV. By varying the chromium content, it is possible to form a material with thermal and electrical conductivities controllable over a wide range.