Poly[(μ3-camphorato-κ3O:O′:O′′)(2-methyl-1H-imidazole-κN3)zinc(II)]

oleh: Haochen Shi, Chunjie Li, Feng Gao, Jingyan Chen, Fei Han

Format: Article
Diterbitkan: International Union of Crystallography 2010-04-01

Deskripsi

In the title compound, [Zn(C10H14O4)(C4H6N2)]n, each ZnII ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetrahedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three ZnII ions, forming two-dimensional layers, which interact further via N—H...O hydrogen bonds.