Structure-property relationships of photofunctional diiridium(II) complexes with tetracationic charge and an unsupported Ir–Ir bond
oleh: Fangrui Zheng, Yuhong Yang, Siye Wu, Shunan Zhao, Yifan Zhu, Huimin Su, Jun-Feng Dai, Zeyin Yan, Lung Wa Chung, Keith Man-Chung Wong
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2022-11-01 |
Deskripsi
Luminescent iridium(III) complexes have several appealing properties such as wide color-tunability and high photo- and chemical stabilities, whereas the properties of related diiridium(II) systems are largely unexplored. Here, the authors synthesize and characterize a series of tetracationic dinuclear iridium(II) complexes, which feature unsupported Ir(II)–Ir(II) single bonds and exhibit photoluminescence in various media.