Preparation and Characterization of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 Complexes
oleh: Hossein Aghabozorg, Robabeh Alizadeh
| Format: | Article |
|---|---|
| Diterbitkan: | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1994-12-01 |
Deskripsi
We have recently synthesized Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 complexes. The reaction of TiCl3(THF)3 with NaBH4 in dry THF gave flat blue crystals, Ti(BH4)3(THF)3. The reaction of VCl3 with NaBH4 in presence of N, N, N', N'- tetramethylethylenediamine, TMEDA, produced violet crystals, V(BH4)2(TMEDA)2. Vibrational and magnetic properties of Ti(BH4)3(THF)3 and V(BH4)2(TMEDA)2 have been studied.