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A unified strategy toward total syntheses of lindenane sesquiterpenoid [4 + 2] dimers
oleh: Biao Du, Zhengsong Huang, Xiao Wang, Ting Chen, Guo Shen, Shaomin Fu, Bo Liu
Format: | Article |
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Diterbitkan: | Nature Portfolio 2019-04-01 |
Deskripsi
Of the 3 classes of dimeric lindenane sesquiterpenoids, only type I And II have been targeted in total synthesis. Here, the authors report a unified strategy to synthetically access the 3 classes of lindenane sesquiterpenoids dimers by developing a [4 + 2] cycloaddition between a common furyl diene and various dienophiles.