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We experimentally investigated the photo-induced direct current (DC) drift of a lead lanthanum zirconate titanate (PLZT) Mach-Zehnder modulator with large optical input power. We clarify the mechanism by which short-term and long-term DC drifts arise and discuss each case of DC drift. We reveal that short-term DC drift can be reduced by adjusting the buffer-layer resistivity of the PLZT modulator. We also found that the impurity level of the buffer layer affects long-term DC drift.