Synthesis and Characterization of Cerium(IV) Metallocenes

oleh: Andrew D. Sutton, David L. Clark, Brian L. Scott, John C. Gordon

Format: Article
Diterbitkan: MDPI AG 2015-12-01

Deskripsi

By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.