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Synthesis and Characterization of Cerium(IV) Metallocenes
oleh: Andrew D. Sutton, David L. Clark, Brian L. Scott, John C. Gordon
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2015-12-01 |
Deskripsi
By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.