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The present paper describes the technological solution for obtaining Cu, Zn, Pb, and Ag from jarosite waste raw material, with its simultaneous separation from In and Fe. By roasting at low temperatures, iron was transformed from the Fe₂(SO₄)₃ form into Fe₂O₃, which is insoluble in water and slightly soluble in acid. Copper sulfate and zinc sulfate are present in jarosite as sulfates. During temperature roasting, the copper and zinc were still in the form of CuSO₄ and ZnSO₄, i.e., they were easily dissolved in water. This procedure led to good selectivity of Cu and Zn compared to Fe. After water leaching, PbSO₄ and Ag₂SO₄ remained in the solid residue. By treating jarosite with a content of 0.7% Cu, 5.39% Zn, and 5.68% Pb, products of commercial quality were obtained. By roasting jarosite in an electric furnace and leaching the roasted sample in water, leaching degrees of 91.07%, 91.97%, and 9.60% were obtained for Cu, Zn, and Fe, respectively. Using 1 M NaOH in the leaching solution, 99.93% Fe was precipitated to pH = 4. Cu in the form of CuSO₄ was further treated by cementation with Zn, after which cement copper was obtained as a commercial product. Zn in the form of ZnSO₄ was further treated by precipitation with Na₂CO₃ to obtain ZnCO₃ concentrate of commercial grade. The total recovery of Pb and Ag, which were treated by chloride leaching, was 96.05% and 87.5%, respectively. The resulting NaPbCl₃ solution was further treated with Na₂CO₃ solution, whereby PbCO₃ was obtained as a commercial product. The produced PbCO₃ could be further subjected to roasting to obtain soluble PbO. In these investigations, PbCO₃ was smelted where a Pb anode was obtained; this was electrolytically refined to a Pb cathode. The proposed process does not pollute the environment with As and Cd.