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The heating load of intermittent heating is not always lower than that of continuous heating for heat storage and release of internal walls. Therefore, the threshold value of daily operation hours exists, and is affected by the configuration of internal walls. A comparative study is performed between continuous and intermittent heating modes to investigate the threshold value of daily operation hours for different internal wall configurations by employing computational fluid dynamic (CFD) models. Meanwhile, field tests on the temperature distribution within a thermal mass was carried out to validate the simulation. The results show that the heating load index of intermittent heating is larger than that of continuous heating with increased amplitude ranging from 31.58% to 152.63%. The threshold value of daily operation hours is, respectively, 18.04 h, 15.80 h, 14.59 h, and 13.46 h for four internal wall configurations. Moreover, with the increase in the insulation level of internal walls, the threshold value of daily operation hours decreases. In addition, the results indicate that it is more economical to use continuous heating when the daily operation hours are more than the threshold values.