A one-dimensional zigzag coordination polymer: catena-poly[[[triaquacadmium(II)]-[μ-2,2′-(5-methyl-1,3-phenylenedioxy)diacetato-κ4O,O′:O′′,O′′′]] monohydrate]
oleh: Hong-Tao Zhang, Xian-Wen Wei, Yun Wei, Ying Lin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-02-01 |
Deskripsi
In the title one-dimensional coordination polymer, {[Cd(C11H10O6)(H2O)3]·H2O}n, the 2,2′-(5-methyl-1,3-phenylenedioxy)diacetate dianions connect CdII ions in a head-to-tail fashion to generate zigzag chains. The coordination geometry of the Cd atom is distorted pentagonal bipyramidal. There are O—H...O hydrogen bonds between the carboxyl O atoms, the aqua ligands and the uncoordinated water molecules.