Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States
oleh: J. Li, J. Mao, A. M. Fiore, R. C. Cohen, R. C. Cohen, J. D. Crounse, A. P. Teng, P. O. Wennberg, P. O. Wennberg, B. H. Lee, F. D. Lopez-Hilfiker, J. A. Thornton, J. Peischl, J. Peischl, I. B. Pollack, T. B. Ryerson, P. Veres, P. Veres, J. M. Roberts, J. A. Neuman, J. A. Neuman, J. B. Nowak, J. B. Nowak, G. M. Wolfe, G. M. Wolfe, T. F. Hanisco, A. Fried, H. B. Singh, J. Dibb, F. Paulot, F. Paulot, L. W. Horowitz
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2018-02-01 |
Deskripsi
Widespread efforts to abate ozone (O<sub>3</sub>) smog have significantly reduced emissions of nitrogen oxides (NO<sub><i>x</i></sub>) over the past 2 decades in the Southeast US, a place heavily influenced by both anthropogenic and biogenic emissions. How reactive nitrogen speciation responds to the reduction in NO<sub><i>x</i></sub> emissions in this region remains to be elucidated. Here we exploit aircraft measurements from ICARTT (July–August 2004), SENEX (June–July 2013), and SEAC<sup>4</sup>RS (August–September 2013) and long-term ground measurement networks alongside a global chemistry–climate model to examine decadal changes in summertime reactive oxidized nitrogen (RON) and ozone over the Southeast US. We show that our model can reproduce the mean vertical profiles of major RON species and the total (NO<sub><i>y</i></sub>) in both 2004 and 2013. Among the major RON species, nitric acid (HNO<sub>3</sub>) is dominant (∼ 42–45 %), followed by NO<sub><i>x</i></sub> (31 %), total peroxy nitrates (ΣPNs; 14 %), and total alkyl nitrates (ΣANs; 9–12 %) on a regional scale. We find that most RON species, including NO<sub><i>x</i></sub>, ΣPNs, and HNO<sub>3</sub>, decline proportionally with decreasing NO<sub><i>x</i></sub> emissions in this region, leading to a similar decline in NO<sub><i>y</i></sub>. This linear response might be in part due to the nearly constant summertime supply of biogenic VOC emissions in this region. Our model captures the observed relative change in RON and surface ozone from 2004 to 2013. Model sensitivity tests indicate that further reductions of NO<sub><i>x</i></sub> emissions will lead to a continued decline in surface ozone and less frequent high-ozone events.