Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer
oleh: Rajesh Kancherla, Krishnamoorthy Muralirajan, Bholanath Maity, Safakath Karuthedath, Gadde Sathish Kumar, Frédéric Laquai, Luigi Cavallo, Magnus Rueping
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2022-05-01 |
Deskripsi
Although the combination of photo- and nickel catalysis has garnered intense interest in the preceding years, the mechanisms by which these transformations occur are to some degree unresolved. Here the authors provide computational and spectroscopic support for a Dexter energy-transfer mechanism in the context of a C(sp3)–H alkylation.