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Carbones and Carbon Atom as Ligands in Transition Metal Complexes
oleh: Lili Zhao, Chaoqun Chai, Wolfgang Petz, Gernot Frenking
Format: | Article |
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Diterbitkan: | MDPI AG 2020-10-01 |
Deskripsi
This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL<sub>2</sub> as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL<sub>2</sub>. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR<sub>3</sub> → [M]-CR<sub>2</sub> → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.