Ag Nanoparticle-Decorated MoS<sub>2</sub> Nanosheets for Enhancing Electrochemical Performance in Lithium Storage

oleh: Thang Phan Nguyen, Il Tae Kim

Format: Article
Diterbitkan: MDPI AG 2021-03-01

Deskripsi

Metallic phase 1T MoS<sub>2</sub> is a well-known potential anode for enhancing the electrochemical performance of lithium-ion batteries owing to its mechanical/chemical stability and high conductivity. However, during the lithiation/delithiation process, MoS<sub>2</sub> nanosheets (NSs) tend to restack to form bulky structures that deteriorate the cycling performance of bare MoS<sub>2</sub> anodes. In this study, we prepared Ag nanoparticle (NP)-decorated 1T MoS<sub>2</sub> NSs via a liquid exfoliation method with lithium intercalation and simple reduction of AgNO<sub>3</sub> in NaBH<sub>4</sub>. Ag NPs were uniformly distributed on the MoS<sub>2</sub> surface with the assistance of 3-mercapto propionic acid. Ag NPs with the size of a few nanometers enhanced the conductivity of the MoS<sub>2</sub> NS and improved the electrochemical performance of the MoS<sub>2</sub> anode. Specifically, the anode designated as Ag3@MoS<sub>2</sub> (prepared with AgNO<sub>3</sub> and MoS<sub>2</sub> in a weight ratio of 1:10) exhibited the best cycling performance and delivered a reversible specific capacity of 510 mAh·g<sup>−1</sup> (approximately 73% of the initial capacity) after 100 cycles. Moreover, the rate performance of this sample had a remarkable recovery capacity of ~100% when the current decreased from 1 to 0.1 A·g<sup>−1</sup>. The results indicate that the Ag nanoparticle-decorated 1T MoS<sub>2</sub> can be employed as a high-rate capacity anode in lithium-ion storage applications.