PA6 and Halloysite Nanotubes Composites with Improved Hydrothermal Ageing Resistance: Role of Filler Physicochemical Properties, Functionalization and Dispersion Technique

oleh: Valentina Sabatini, Tommaso Taroni, Riccardo Rampazzo, Marco Bompieri, Daniela Maggioni, Daniela Meroni, Marco Aldo Ortenzi, Silvia Ardizzone

Format: Article
Diterbitkan: MDPI AG 2020-01-01

Deskripsi

Polyamide 6 (PA6) suffers from fast degradation in humid conditions due to hydrolysis of amide bonds, which limits its durability. The addition of nanotubular fillers represents a viable strategy for overcoming this issue, although the additive/polymer interface at high filler content can become privileged site for moisture accumulation. As a cost-effective and versatile material, halloysite nanotubes (HNT) were investigated to prepare PA6 nanocomposites with very low loadings (1&#8722;45% w/w). The roles of the physicochemical properties of two differently sourced HNT, of filler functionalization with (3-aminopropyl)triethoxysilane and of dispersion techniques (<i>in situ</i> polymerization vs. melt blending) were investigated. The aspect ratio (5 vs. 15) and surface charge (&#8722;31 vs. &#8722;59 mV) of the two HNT proved crucial in determining their distribution within the polymer matrix. <i>In situ</i> polymerization of functionalized HNT leads to enclosed and well-penetrated filler within the polymer matrix. PA6 nanocomposites crystal growth and nucleation type were studied according to Avrami theory, as well as the formation of different crystalline structures (&#945; and &#947; forms). After 1680 h of ageing, functionalized HNT reduced the diffusion of water into polymer, lowering water uptake after 600 h up to 90%, increasing the materials durability also regarding molecular weights and rheological behavior.