Optimal control theory enables homonuclear decoupling without Bloch–Siegert shifts in NMR spectroscopy

oleh: Paul W. Coote, Scott A. Robson, Abhinav Dubey, Andras Boeszoermenyi, Mengxia Zhao, Gerhard Wagner, Haribabu Arthanari

Format: Article
Diterbitkan: Nature Portfolio 2018-08-01

Deskripsi

Bloch–Siegert shifts prevent the accurate observation of resonance frequencies in NMR experiments. Here the authors present a method for homonuclear decoupling that avoids inducing Bloch–Siegert shifts and improves the sensitivity and resolution of HNCA experiments.