(μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate
oleh: L.-J. Han
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-02-01 |
Deskripsi
The title compound, [Mo2(C15H15N2O2)3(C7H5O2)]·CH2Cl2, has a quadruply bonded Mo24+ unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2.