(Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ81:2O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)samarium(III)
oleh: Wen-Bin Sun, Peng-Fei Yan, Hong-Feng Li, Ting Gao, Guang-Ming Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-07-01 |
Deskripsi
In the title heteronuclear complex, [CuSm(C19H20N2O4)(NO3)3(CH3COCH3)], the CuII ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and by an O atom from the acetone molecule in a square-pyramidal geometry. The SmIII ion is ten-coordinated by six O atoms from the three nitrate ligands and four O atoms from the L ligand. In L, the C atoms of the diaminopropane fragment are disordered over two positions in a 0.674 (10):0.326 (10) ratio.