Methoxo[N′-(3-methoxy-2-oxidobenzylidene)benzohydrazidato]oxidovanadium(V)
oleh: Shu-Mei Huang, Fei-Feng Jiang, Xiao-Hua Chen, Qiong-Jie Wu
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-04-01 |
Deskripsi
In the title complex, [V(C15H12N2O4)(CH3O)O], the VV ion exhibits a distorted square-pyramidal coordination geometry; three donor atoms from a hydrazone ligand and one O atom of the deprotonated methanol define the coordination basal plane. The VV ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom. Intramolecular O—H...N hydrogen bonding occurs. Intermolecular C—H...O hydrogen bonding is also observed in the crystal structure.