(Acetato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)copper(II) trifluoroacetate tetrahydrate
oleh: Jinxia Wang, Zhuping Jin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-07-01 |
Deskripsi
In the title compound, [Cu(CH3CO2)(C12H8N2)2](CF3CO2)·4H2O, the CuII atom shows a distorted octahedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong intermolecular O—H...O hydrogen-bonding interactions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio.