Suppressing hydrogen peroxide generation to achieve oxygen-insensitivity of a [NiFe] hydrogenase in redox active films
oleh: Huaiguang Li, Ute Münchberg, Alaa A. Oughli, Darren Buesen, Wolfgang Lubitz, Erik Freier, Nicolas Plumeré
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2020-02-01 |
Deskripsi
Oxidative degradation impedes practical applications of highly active but fragile catalysts. Here the authors show that combining a protection matrix for O2 reduction and hydrogen peroxide decomposition stabilizes highly O2-sensitive hydrogenase in the harsh oxidative conditions of operating fuel cells.