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In-Depth Understanding of Hardmetal Corrosion Performance Reveals a Path to the Electrochemical Demolition of Scrap
oleh: Benedetto Bozzini, Francesco Tavola, Augusto Travella, Alessandro Alleva, Claudio Mele, Elisa Emanuele, Sandra Tedeschi, Gian Pietro De Gaudenzi
Format: | Article |
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Diterbitkan: | MDPI AG 2023-07-01 |
Deskripsi
Recycling of hardmetal scrap is strategic for critical raw materials recovery. Available recycling processes are polluting and have a large carbon footprint. Attempts to exploit controlled corrosion failed in industrial practice, owing to self-limiting processes. We revisit the corrosion route, in view of gaining the fundamental knowledge enabling high-throughput recovery. We selected the worst-case approach of highly corrosion-resistant CoNiWC-based hardmetal grades and neutral aqueous electrolyte at room temperature. Systematic electrochemical measurements, UV–Vis spectroscopy and SEM microscopy disclosed that, even though there is no hope to overcome the self-limiting corrosion rate, nevertheless, by exploiting the mechanical action of anodic O<sub>2</sub> evolution acting precisely at the interface between the residual active material and the corrosion film, the latter can be efficiently removed, periodically reactivating the hardmetal corrosion in a way that results in an ultra-high scrap destruction rate, of interest for real-life industrial processes.