catena-Poly[bis(dimethylazanium) [[chloridocopper(II)]-di-μ-chlorido-[chloridocopper(II)]-di-μ-azido-κ4N:N]]

oleh: Wei-Yi Zhang, Li Yang, Jie Liu

Format: Article
Diterbitkan: International Union of Crystallography 2011-12-01

Deskripsi

The crystal structure of the title complex, {(C2H8N)[CuCl2(N3)]}n, exhibits inorganic chains consisting of Cu(II) cations as well azide and chloride anions. The chains, made up from Cu—Cl—Cu—N—Cu linkages, are aligned parallel to the c axis. This architecture is further stabilized by a number of N—H...Cl hydrogen bonds involving the protonated charge-compensating dimethylamine cations and chloride atoms.