Benzyl 2-methyl-3-[(E)-(thiophen-2-yl)methylidene]dithiocarbazate
oleh: Saroj K. S. Hazari, B. K. Dey, Tapashi G. Roy, B. Ganguly, Seik Weng Ng, Edward R. T. Tiekink
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-04-01 |
Deskripsi
In the title compound, C14H14N2S3, the thione S atom and methyl group are syn, as are the two thioether S atoms. The molecule is twisted, the dihedral angles between the central (C2N2S2) residue and the pendent 2-thienyl and phenyl rings being 21.57 (6) and 77.54 (3)°, respectively. In the crystal, molecules assemble into a three-dimensional architecture via C—H...π interactions, involving both the five- and six-membered rings as acceptors, as well as S...S interactions [3.3406 (5) Å] between centrosymmetrically related 2-thienyl rings.