Gold Nanoclusters Grown on MoS<sub>2</sub> Nanosheets by Pulsed Laser Deposition: An Enhanced Hydrogen Evolution Reaction

oleh: Yuting Jing, Ruijing Wang, Qiang Wang, Xuefeng Wang

Format: Article
Diterbitkan: MDPI AG 2021-12-01

Deskripsi

Au nanoparticles were decorated on a 2H MoS<sub>2</sub> surface to form an Au/MoS<sub>2</sub> composite by pulse laser deposition. Improved HER activity of Au/MoS<sub>2</sub> is evidenced by a positively shifted overpotential (−77 mV) at a current density of −10 mA cm<sup>−2</sup> compared with pure MoS<sub>2</sub> nanosheets. Experimental evidence shows that the interface between Au and MoS<sub>2</sub> provides more sites to combine protons to form an active H atom. The density functional theory calculations found that new Au active sites on the Au and MoS<sub>2</sub> interface with improved conductivity of the whole system are essential for enhancing HER activity of Au/MoS<sub>2</sub>.