Variations in O<sub>3</sub>, CO, and CH<sub>4</sub> over the Bay of Bengal during the summer monsoon season: shipborne measurements and model simulations

oleh: I. A. Girach, N. Ojha, P. R. Nair, A. Pozzer, Y. K. Tiwari, K. R. Kumar, J. Lelieveld

Format: Article
Diterbitkan: Copernicus Publications 2017-01-01

Deskripsi

We present shipborne measurements of surface ozone (O<sub>3</sub>), carbon monoxide (CO), and methane (CH<sub>4</sub>) over the Bay of Bengal (BoB), the first time such measurements have been performed during the summer monsoon season, as a part of the Continental Tropical Convergence Zone (CTCZ) experiment during 2009. O<sub>3</sub>, CO, and CH<sub>4</sub> mixing ratios exhibited significant spatial and temporal variability in the ranges of 8–54 nmol mol<sup>−1</sup>, 50–200 nmol mol<sup>−1</sup>, and 1.57–2.15 µmol mol<sup>−1</sup>, with means of 29.7 ± 6.8 nmol mol<sup>−1</sup>, 96 ± 25 nmol mol<sup>−1</sup>, and 1.83 ± 0.14 µmol mol<sup>−1</sup>, respectively. The average mixing ratios of trace gases over BoB in air masses from central/northern India (O<sub>3</sub>: 30 ± 7 nmol mol<sup>−1</sup>; CO: 95 ± 25 nmol mol<sup>−1</sup>; CH<sub>4</sub>: 1.86 ± 0.12 µmol mol<sup>−1</sup>) were not statistically different from those in air masses from southern India (O<sub>3</sub>: 27 ± 5 nmol mol<sup>−1</sup>; CO: 101 ± 27 nmol mol<sup>−1</sup>; CH<sub>4</sub>: 1.72 ± 0.14 µmol mol<sup>−1</sup>). Spatial variability is observed to be most significant for CH<sub>4</sub> with higher mixing ratios in the air masses from central/northern India, where higher CH<sub>4</sub> levels are seen in the SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CartograpHY) data. O<sub>3</sub> mixing ratios over the BoB showed large reductions (by  ∼  20 nmol mol<sup>−1</sup>) during four rainfall events. Temporal changes in the meteorological parameters, in conjunction with O<sub>3</sub> vertical profile, indicate that these low-O<sub>3</sub> events are associated with downdrafts of free-tropospheric O<sub>3</sub>-poor air masses. While the observed variations of O<sub>3</sub> and CO are successfully reproduced using the Weather Research and Forecasting model with Chemistry (WRF-Chem), this model overestimates mean concentrations by about 6 and 16 % for O<sub>3</sub> and CO, respectively, generally overestimating O<sub>3</sub> mixing ratios during the rainfall events. An analysis of modelled O<sub>3</sub> along air mass trajectories show mean en route O<sub>3</sub> production rate of about 4.6 nmol mol<sup>−1</sup> day<sup>−1</sup> in the outflow towards the BoB. Analysis of the various tendencies from model simulations during an event on 10 August 2009, reproduced by the model, shows horizontal advection rapidly transporting O<sub>3</sub>-rich air masses from near the coast across the BoB. This study fills a gap in the availability of trace gas measurements over the BoB and, when combined with data from previous campaigns, reveals large seasonal amplitude ( ∼  39 and  ∼  207 nmol mol<sup>−1</sup> for O<sub>3</sub> and CO, respectively) over the northern BoB.