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From perfluoroalkyl aryl sulfoxides to ortho thioethers
oleh: Yang Li, Guillaume Dagousset, Emmanuel Magnier, Bruce Pégot
Format: | Article |
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Diterbitkan: | Beilstein-Institut 2024-08-01 |
Deskripsi
Access to original ortho thioether derivatives was achieved through a [3,3]-rearrangement in a one-pot two-step protocol. Several aryl-SCF3 compounds are reported by variation of the nitrile or of the trifluoroalkyl sulfoxide starting material. The variation of the perfluoroalkyl chain was also possible.