Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
oleh: Hamid Khaledi, Hapipah Mohd Ali
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-02-01 |
Deskripsi
The PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent molecules via an N—H...N interaction. The crystal structure is consolidated by intermolecular C—H...S interactions.