Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2O,O′}tris(thiocyanato-κN)cerium(III)
oleh: Jian-Feng Liu, Hui-Duo Xian, Guo-Liang Zhao
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-06-01 |
Deskripsi
The asymmetric unit of the title compound, [Ce(NCS)3(C15H15NO2)3], contains three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands and three independent thiocyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine.