Bis(carbonyl-κC)(N,N-dimethylthiocarbamoyl-κ2C,S)(pyridine-2-thiolato-κ2N,S)(triphenylphosphine-κP)molybdenum(II)
oleh: Gene-Hsiang Lee, Hsiao-Fen Wang, Kuang-Hway Yih
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-10-01 |
Deskripsi
There are two independent molecules with similar configurations in the title complex, [Mo(C3H6NS)(C5H4NS)(C18H15P)(CO)2]. The geometry around the metal atom is that of a capped octahedron. The thiocabamoyl and pyridine-2-thiolate ligands coordinate to the molybdenum metal center through the C and S atoms, and N and S atoms, respectively. NMR, IR and MS analyses are in agreement with the structure of the title compound.