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Bedded barite, Fe-Zn-Pb sulfides, carbonates, and cherts within Ediacaran (Dalradian Supergroup) graphitic metasediments near Aberfeldy in Scotland have previously been interpreted as chemical sediments precipitated from hydrothermal fluids episodically exhaled into marine basins filled with organic-rich mud, silt, and sand. Lithological variation and compositional diversity in pyrite and sphalerite reflect varied redox environments and proximity to hydrothermal discharges. Thick beds (>2 m) of barite have relatively uniform δ³⁴S of +36 ± 1.5‰, considered to represent contemporaneous seawater sulfate, as negative Δ¹⁷O indicates incorporation of atmospheric oxygen during precipitation in the water column. However, certain features suggest that diagenetic processes involving microbial sulfate reduction modified the mineralogy and isotopic composition of the mineralization. Barite bed margins show decimeter-scale variation in δ³⁴S (+32 to +41‰) and δ¹⁸O (+8 to +21‰), attributed to fluid-mediated transfer of dissolved barium and sulfate between originally porous barite and adjacent sediments, in which millimetric sulfate crystals grew across sedimentary lamination. Encapsulated micron-sized barium carbonates indicate early diagenetic barite dissolution with incorporation of sulfur into pyrite, elevating pyrite δ³⁴S. Subsequently, sulfidation reactions produced volumetrically minor secondary barite with δ³⁴S of +16 to +22‰. Overall, these processes affected small volumes of the mineralization, which originally formed on the seafloor as a classic SEDEX deposit.