cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
oleh: Sadif A. Shirvan, Sara Haydari Dezfuli, Elyas Golabi, Mohammad Amin Gholamzadeh
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-10-01 |
Deskripsi
In the title compound, [VClO(C12H12N2)2]Cl·C2H5OH·H2O, the VIV atom is six-coordinated in a distorted octahedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H...Cl, C—H...O and C—H...Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intramolecular C—H...O and C—H...Cl hydrogen bonds are also present.