<i>In Situ</i> Hyperspectral Raman Imaging: A New Method to Investigate Sintering Processes of Ceramic Material at High-temperature

oleh: Kerstin Hauke, Johannes Kehren, Nadine Böhme, Sinje Zimmer, Thorsten Geisler

Format: Article
Diterbitkan: MDPI AG 2019-03-01

Deskripsi

In the last decades, Raman spectroscopy has become an important tool to identify and investigate minerals, gases, glasses, and organic material at room temperature. In combination with high-temperature and high-pressure devices, however, the <i>in situ</i> investigation of mineral transformation reactions and their kinetics is nowadays also possible. Here, we present a novel approach to <i>in situ</i> studies for the sintering process of silicate ceramics by hyperspectral Raman imaging. This imaging technique allows studying high-temperature solid-solid and/or solid-melt reactions spatially and temporally resolved, and opens up new avenues to study and visualize high-temperature sintering processes in multi-component systems. After describing in detail the methodology, the results of three application examples are presented and discussed. These experiments demonstrate the power of hyperspectral Raman imaging for <i>in situ</i> studies of the mechanism(s) of solid-solid or solid-melt reactions at high-temperature with a micrometer-scale resolution as well as to gain kinetic information from the temperature- and time-dependent growth and breakdown of minerals during isothermal or isochronal sintering.