Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)(dimethylformamide-κO)indium(III) hemihydrate
oleh: Sadif A. Shirvan, Sara Haydari Dezfuli, Fereydoon Khazali, Manouchehr Aghajeri, Ali Borsalani
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-12-01 |
Deskripsi
The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent InIII complex molecules with similar structures and one lattice water molecule. In each complex molecule, the InIII atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O—H...Cl hydrogen bonds. Further weak C—H...Cl and C—H...O hydrogen bonds result in the formation of a three-dimensional structure.