trans-Dichloridobis[dicyclohexyl(4-isopropylphenyl)phosphane-κP]platinum(II) acetone monosolvate
oleh: Bubele Vuba, Alfred Muller
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
The title compound, [PtCl2(C21H33P)2]·C3H6O, crystallizes with an accompanying acetone solvent molecule. The metal atom shows a distorted square-planar coordination environment, with a P—Pt—P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2). The solvent molecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%.