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Kinetics and the Effect of Thermal Treatments on the Martensitic Transformation and Magnetic Properties in Ni<sub>49</sub>Mn<sub>32</sub>Ga<sub>19</sub> Ferromagnetic Shape Memory Ribbons
oleh: Felicia Tolea, Bogdan Popescu, Cristina Bartha, Monica Enculescu, Mugurel Tolea, Mihaela Sofronie
Format: | Article |
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Diterbitkan: | MDPI AG 2022-12-01 |
Deskripsi
In our work, the kinetics of martensitic transformations and the influence of thermal treatments on martensitic transformations, as well as the related magnetic properties of the Ni<sub>49</sub>Mn<sub>32</sub>Ga<sub>19</sub> ferromagnetic shape memory melt-spun ribbons, have been investigated. Thermal treatments at 673 K for 1, 4 and 8 h can be considered an instrument for fine-tuning the performance parameters of alloys. One-hour thermal treatments promote an improvement in the crystallinity of these otherwise highly textured ribbons, reducing internal defects and stress induced by the melt-spinning technique. Longer thermal treatments induce an important magnetization rise concomitantly with a slight and continuous increase in martensitic temperatures and transformation enthalpy. The activation energy, evaluated from differential scanning calorimeter experimental data with a Friedman model, significantly increases after thermal treatments as a result of the multi-phase coexistence and stabilization of the non-modulated martensitic phase, which increases the reverse martensitic transformation hindrance.