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Stereoselective one-pot synthesis of polypropionates
oleh: Guo-Ming Ho, Medel Manuel L. Zulueta, Shang-Cheng Hung
Format: | Article |
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Diterbitkan: | Nature Portfolio 2017-09-01 |
Deskripsi
Polypropionates are present in many natural products possessing high bioactivity and therapeutic value. Here the authors show a strategy for the stereoselective assembly of polypropionates with three or four stereocentres through a process that includes a Diels–Alder reaction, silylenol ether hydrolysis and Baeyer–Villiger oxidation.