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We developed a new nanowire for enhancing the performance of lithium-sulfur batteries. In this study, we synthesized WO₃ nanowires (WNWs) via a simple hydrothermal method. WNWs and one-dimensional materials are easily mixed with carbon nanotubes (CNTs) to form interlayers. The WNW interacts with lithium polysulfides through a thiosulfate mediator, retaining the lithium polysulfide near the cathode to increase the reaction kinetics. The lithium-sulfur cell achieves a very high initial discharge capacity of 1558 and 656 mAh g⁻¹ at 0.1 and 3 C, respectively. Moreover, a cell with a high sulfur mass loading of 4.2 mg cm⁻² still delivers a high capacity of 1136 mAh g⁻¹ at a current density of 0.2 C and it showed a capacity of 939 mAh g⁻¹ even after 100 cycles. The WNW/CNT interlayer maintains structural stability even after electrochemical testing. This excellent performance and structural stability are due to the chemical adsorption and catalytic effects of the thiosulfate mediator on WNW.