Dissymmetry enhancement in enantioselective synthesis of helical polydiacetylene by application of superchiral light
oleh: Chenlu He, Guang Yang, Yan Kuai, Sizhen Shan, Lin Yang, Jingang Hu, Douguo Zhang, Qijin Zhang, Gang Zou
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2018-11-01 |
Deskripsi
Superchiral light can be utilized to promote asymmetric photochemical reactions. Here the authors show that superchiral light imparts greater chiral bias to trigger asymmetric photo-polymerization reactions from initially achiral diacetylene monomers and enhanced optical dissymmetry in polydiacetylene films.