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2-(Fluoromethyl)-4,7-dimethoxy-1-methyl-1<i>H</i>-benzimidazole
oleh: Patrick Kielty, Pau Farrà s, Dennis A. Smith, Fawaz Aldabbagh
Format: | Article |
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Diterbitkan: | MDPI AG 2020-05-01 |
Deskripsi
Selectfluor (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)) substitutes the TEMPO free radical with fluorine on 4,7-dimethoxy-1-methyl-2-{[(2,2,6,6-tetramethylpiperidin-1-yl)oxy]methyl}-1<i>H</i>-benzimidazole to give the title compound in a 77% yield. A mechanism is proposed for the formation of this novel methylene fluoride.