trans-Bis{1-[2-(2,6-diisopropylanilino)phenyl]-3-isopropylimidazolin-2-ylidenyl-κC2}diiodidopalladium(II) benzene disolvate
oleh: Christopher G. Daly, Kuldip Singh, Warren B. Cross
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-06-01 |
Deskripsi
In the title complex, [PdI2(C24H31N3)2]·2C6H6, the Pd2+ ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I2C2 square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I—Pd—C—N torsion angles of −81.1 (6) and −78.2 (5)°. The Pd—carbene and Pd—I distances are 2.016 (6) and 2.5971 (10) Å, respectively.