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Photochemical Aryl Radical Cyclizations to Give (E)-3-Ylideneoxindoles
oleh: Michael Gurry, Ingrid Allart-Simon, Patrick McArdle, Stéphane Gérard, Janos Sapi, Fawaz Aldabbagh
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2014-09-01 |
Deskripsi
(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts.