Photoluminescent Spectral Broadening of Lead Halide Perovskite Nanocrystals Investigated by Emission Wavelength Dependent Lifetime

oleh: Jinlei Zhang, Jiuyang He, Lun Yang, Zhixing Gan

Format: Article
Diterbitkan: MDPI AG 2020-03-01

Deskripsi

Despite intensive efforts, the fluorescence of perovskite nanocrystals (NCs) still suffers from a poor color purity, which limits the applications in light emitting and multicolor display. A deep understanding on the fundamental of the photoluminescent (PL) spectral broadening is thus of great significance. Herein, the PL decay curves of the CsPbCl<sub>x</sub>Br<sub>3-x</sub> NCs are monitored at different wavelengths covering the entire PL band. Moreover, energy relaxation time &#964; and radiative recombination time &#946; are obtained by numerical fittings. The dependences of &#964; and 1/&#946; on the detection wavelength agree well with the steady-state PL spectrum, indicating the observed PL broadening is an intrinsic effect due to the resonance and off-resonance exciton radiative recombination processes. This work not only provides a new analysis method for time-resolved PL spectra of perovskites, but also gains a deep insight into the spectral broadening of the lead halide perovskite NCs.