Tris(1,10-phenanthroline)iron(II) μ-oxido-bis[trichloridoferrate(III)]
oleh: Chun Ling, Li Song, Xinping Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-09-01 |
Deskripsi
In the title salt, [Fe(C12H8N2)3][Fe2Cl6O], the ionic components are linked into a two-dimensional supramolecular layer by two pairs of C—H...Cl hydrogen bonds and π–π stacking interactions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent FeII–FeIII compound, in which an FeII atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two FeIII atoms in tetrahedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intramolecular C—H...N hydrogen bonds are observed.