Bis(μ2-3,5-diisopropyl-4H-1,2,4-triazole-κ2N1:N2)bis[(nitrato-κO)silver(I)]
oleh: Guang Yang, Seik Weng Ng, Ying-Li Wang, Zhao-Yang Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-08-01 |
Deskripsi
The neutral N-heterocycle in the title centrosymmetric dinuclear compound, [Ag2(NO3)2(C8H15N3)2], bridges two metal atoms through its imino N atoms. The N—Ag—N skeleton is bent [N—Ag—N = 127.2 (3)°]; as one of two O atoms of the nitrate anion is nearly coplanar with this N—Ag—N skeleton [Ag—O = 2.63 (1) Å], the coordination geometry around the AgI atom is regarded as trigonal-planar. One of the two isopropyl groups is disordered over two positions in respect of the methyl groups in a 1:1 ratio. In the crystal structure, intermolecular N—H...O hydrogen bonding is observed between the nitrate groups and triazole ligands.